Isotope Effects on Equilibrium Constants of Chemical Reactions; Transition State Theory of Isotope Effects
作者： Max Wolfsberg , W Alexander Hook , Piotr Paneth , Luís Paulo N Rebelo , Max Wolfsberg
DOI: 10.1007/978-90-481-2265-3_4
关键词:
摘要: The statistical thermodynamic theory of isotope effects on chemical equilibrium constants is developed in detail. extension the method to treat kinetic using transition state model briefly described.
springer.com
sci-hub.st 参考文章(10)
Jacob Bigeleisen, Max Wolfsberg, Theoretical and Experimental Aspects of Isotope Effects in Chemical Kinetics Advances in Chemical Physics. pp. 15- 76 ,(2007) , 10.1002/9780470143476.CH2
Jacob Bigeleisen, Nuclear Size and Shape Effects in Chemical Reactions. Isotope Chemistry of the Heavy Elements Journal of the American Chemical Society. ,vol. 118, pp. 3676- 3680 ,(1996) , 10.1021/JA954076K
R. P. Bell, The tunnel effect correction for parabolic potential barriers Transactions of the Faraday Society. ,vol. 55, pp. 1- 4 ,(1959) , 10.1039/TF9595500001
L. Waldmann, Zur Theorie der Isotopentrennung durch Austauschreaktionen Naturwissenschaften. ,vol. 31, pp. 205- 206 ,(1943) , 10.1007/BF01481918
Jacob Bigeleisen, Maria Goeppert Mayer, Calculation of Equilibrium Constants for Isotopic Exchange Reactions The Journal of Chemical Physics. ,vol. 15, pp. 261- 267 ,(1947) , 10.1063/1.1746492
Jacob Bigeleisen, Takanobu Ishida, Application of Finite Orthogonal Polynomials to the Thermal Functions of Harmonic Oscillators. I. Reduced Partition Function of Isotopic Molecules Journal of Chemical Physics. ,vol. 48, pp. 1311- 1330 ,(1968) , 10.1063/1.1668797
MAX WOLFSBERG, LAWRENCE I KLEINMAN, None, Corrections to the Born-Oppenheimer Approximation in the Calculation of Isotope Effects on Equilibrium Constants AMERICAN CHEMICAL SOCIETY. pp. 64- 76 ,(1975) , 10.1021/BK-1975-0011.CH004
Takanobu Ishida, Yasuhiko Fujii, Enrichment of Isotopes CRC Press. pp. 41- 88 ,(2005) , 10.1201/9781420028027.CH2
Max Wolfsberg, Comments on Selected Topics in Isotope Theoretical Chemistry CRC Press. pp. 89- 118 ,(2005) , 10.1201/9781420028027.CH3
Samuel Glasstone, The theory of rate processes ,(1941)