Effects of normalization on feature selection in pyrolysis gas chromatography of coal tar pitches

作者: Matthew S. Klee , Alice M. Harper , L. B. Rogers

DOI: 10.1021/AC00229A014

关键词:

摘要: Computerized calculation of variance weights sometimes detected important features that were not obvious from visual inspections chromatograms for any two three classes coal tar pitches. In addition, normalizations by one or more peak areas heights, procedures often resorted to as a means minimizing the effect differences in size sample heterogeneity, generally resulted decreasing all features. Finally, successful was devised correcting obtained using column had gradually degraded during long series runs.

参考文章(20)
GIANCARLO CRESCENTINI, FABRIZIO BRUNER, Evidence for the presence of Freon 21 in the atmosphere Nature. ,vol. 279, pp. 311- 312 ,(1979) , 10.1038/279311A0
D. R. Cronn, D. E. Harsch, Determination of Atmospheric Halocarbon Concentrations by Gas Chromatography-Mass Spectrometry Analytical Letters. ,vol. 12, pp. 1489- 1496 ,(1979) , 10.1080/00032717908082548
Joseph L. Glajch, J.A. Lubkowitz, L.B. Rogers, Pyrolysis gas chromatography applied to coal tar- and petroleum-pitches Journal of Chromatography A. ,vol. 168, pp. 355- 364 ,(1979) , 10.1016/0021-9673(79)80005-9
H. H. Westberg, R. A. Rasmussen, M. Holdren, Gas chromatographic analysis of ambient air for light hydrocarbons using a chemically bonded stationary phase Analytical Chemistry. ,vol. 46, pp. 1852- 1854 ,(1974) , 10.1021/AC60348A045
A. E. O'Keeffe, G. C. Ortman, Primary Standards for Trace Gas Analysis. Analytical Chemistry. ,vol. 38, pp. 760- 763 ,(1966) , 10.1021/AC60238A022
Fabrizio Bruner, Giuliano Bertoni, Giancarlo Crescentini, Critical evaluation of sampling and gas chromatographic analysis of halocarbons and other organic air pollutants Journal of Chromatography A. ,vol. 167, pp. 399- 407 ,(1978) , 10.1016/S0021-9673(00)91172-5
Göran Blomquist, Erik Johansson, Bengt Söderström, Svante Wold, Data analysis of pyrolysis—chromatograms by means of simca pattern recognition Journal of Analytical and Applied Pyrolysis. ,vol. 1, pp. 53- 65 ,(1979) , 10.1016/0165-2370(79)80005-4
E.P. Grimsrud, R.A. Rasmussen, The analysis of chlorofluorocarbons in the troposphere by gas chromatography-mass spectrometry Atmospheric Environment. ,vol. 9, pp. 1010- 1013 ,(1975) , 10.1016/0004-6981(75)90021-9
S. A. Penkett, N. J. D. Prosser, R. A. Rasmussen, M. A. K. Khalil, Measurements of CHFCl 2 in background tropospheric air Nature. ,vol. 286, pp. 793- 795 ,(1980) , 10.1038/286793A0