Mass spectrometry of aralkyl compounds with a function group—IV : Specific exchange between the α- and Ortho-hydrogen atoms in the molecular ion of γ-phenylpropylbromide
作者： N.M.M. Nibbering , Th.J. de Boer
DOI: 10.1016/0040-4020(68)88094-9
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摘要: Abstract The mass spectrum of γ-phenylpropylbromide has been compared with that analogues, specifically deuterated in the aliphatic chain and Ph ring. It is shown molecular ion a mutual exchange takes place between H atoms from α-methylene group ortho -positions aromatic Moreover, it demonstrated Br atom as well an α-H are transferred to one nucleus via McLafferty rearrangement.
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