Preparation of TiO2 Thin Films Using Inorganic Peroxo Titanic Complex and Autoclaved Sols as Precursors

作者: Lei Ge , Ming Xia Xu , Lei E , Yu Ming Tian , Hai Bo Fang

DOI: 10.4028/WWW.SCIENTIFIC.NET/KEM.280-283.809

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摘要: A new sol-gel method was introduced to prepare titanium oxides (TiO2) photocatalytic thin flms using peroxide (H2O2) and titanyl sulfate (TiOSO4) as raw materials. The TiOSO4 solution recipitated by adding ammonia solution, then peptized with 30% H2O2 get a yellow, table, neutral, transparent liquid (peroxo titanic complex sol). When the peroxo sol autoclaved above 80°C for 2h, it changed stable, semitransparent containing eedle-like, ultra-fine anatase crystals less than 20nm in diameter. Titanium oxide (anatase) films sed photocatalysis can be prepared on substrates dip-coating technique omplex sols.

参考文章(6)
Jinlong Zhang, Madoka Minagawa, Terukazu Ayusawa, Srinivasan Natarajan, Hiromi Yamashita, Masaya Matsuoka, Masakazu Anpo, In Situ Investigation of the Photocatalytic Decomposition of NO on the Ti−HMS under Flow and Closed Reaction Systems Journal of Physical Chemistry B. ,vol. 104, pp. 11501- 11505 ,(2000) , 10.1021/JP002513Y
Tetsu Tatsuma, Shin-ichiro Tachibana, Akira Fujishima, Remote Oxidation of Organic Compounds by UV-Irradiated TiO2 via the Gas Phase Journal of Physical Chemistry B. ,vol. 105, pp. 6987- 6992 ,(2001) , 10.1021/JP011108J
Jimmy C Yu, Jiaguo Yu, Jincai Zhao, Enhanced photocatalytic activity of mesoporous and ordinary TiO2 thin films by sulfuric acid treatment Applied Catalysis B-environmental. ,vol. 36, pp. 31- 43 ,(2002) , 10.1016/S0926-3373(01)00277-6
R.S Sonawane, S.G Hegde, M.K Dongare, Preparation of titanium(IV) oxide thin film photocatalyst by sol–gel dip coating Materials Chemistry and Physics. ,vol. 77, pp. 744- 750 ,(2003) , 10.1016/S0254-0584(02)00138-4
Masakazu Anpo, Utilization of TiO 2 photocatalysts in green chemistry Pure and Applied Chemistry. ,vol. 72, pp. 1265- 1270 ,(2000) , 10.1351/PAC200072071265
Hiromichi ICHINOSE, Makoto TERASAKI, Hiroaki KATSUKI, Synthesis of Peroxo-Modified Anatase Sol from Peroxo Titanic Acid Solution Journal of the Ceramic Society of Japan. ,vol. 104, pp. 715- 718 ,(1996) , 10.2109/JCERSJ.104.715