Preparation, Characterization, and Theoretical Study of Nanoparticles of Triphenylphosphonium Tetrachloroaluminate(III) [P(C6H5)3H]+[AlCl4]−
DOI: 10.1080/15533174.2012.740737
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摘要: Triphenylphosphonium tetrachloroaluminate(III) [P(C6H5)3 H]+[AlCl4]−, TPPTCA, nanoparticle was synthesized by using triphenylphosphonium chloride addition to AlCl3 in the presence of surfactant. The product characterized spectroscopic and analytical methods such as 31P-NMR, FT-IR, XRD, SEM, CHN. Theoretical calculations were used for structural optimization this compound. structure compound has been calculated optimized density functional theory (DFT) based method at B3LYP/6–311G levels theory, Gaussian 03 package programs. comparison between experiment is made. On base application scanning electron microscopy showed about 54 nm particle sizes.
sci-hub.se 参考文章(11)
Wei Zhong Lv, Zhong Kuang Luo, Bo Liu, Xiang Zhong Ren, Hong Hua Cai, Pei Xin Zhang, Jian Hong Liu, Synthesis, Characterization and Magnetism of Nanosized Copper Ferrite Key Engineering Materials. ,vol. 368-372, pp. 604- 606 ,(2008) , 10.4028/WWW.SCIENTIFIC.NET/KEM.368-372.604
Weizhong Lv, Bo Liu, Qi Qiu, Fang Wang, Zhongkuan Luo, Peixin Zhang, Shaohui Wei, Synthesis, characterization and photocatalytic properties of spinel CuAl2O4 nanoparticles by a sonochemical method Journal of Alloys and Compounds. ,vol. 479, pp. 480- 483 ,(2009) , 10.1016/J.JALLCOM.2008.12.111
Jeffrey A. Boon, Joseph A. Levisky, J. Lloyd Pflug, John S. Wilkes, Friedel-Crafts reactions in ambient-temperature molten salts Journal of Organic Chemistry. ,vol. 51, pp. 480- 483 ,(1986) , 10.1021/JO00354A013
Wei-zhong Lv, Bo Liu, Zhong-kuan Luo, Xiang-zhong Ren, Pei-xin Zhang, XRD studies on the nanosized copper ferrite powders synthesized by sonochemical method Journal of Alloys and Compounds. ,vol. 465, pp. 261- 264 ,(2008) , 10.1016/J.JALLCOM.2007.10.049
Enrique G. Yanes, Samuel R. Gratz, Michael J. Baldwin, Sara E. Robison, Apryll M. Stalcup, Capillary electrophoretic application of 1-alkyl-3-methylimidazolium-based ionic liquids. Analytical Chemistry. ,vol. 73, pp. 3838- 3844 ,(2001) , 10.1021/AC010263R
Paulo A.Z Suarez, Jeane E.L Dullius, Sandra Einloft, Roberto F de Souza, Jairton Dupont, TWO-PHASE CATALYTIC HYDROGENATION OF OLEFINS BY RU(II) AND CO(II) COMPLEXES DISSOLVED IN 1-N-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE IONIC LIQUID Inorganica Chimica Acta. ,vol. 255, pp. 207- 209 ,(1997) , 10.1016/S0020-1693(96)05363-7
John S. Wilkes, Joseph A. Levisky, Robert A. Wilson, Charles L. Hussey, Dialkylimidazolium chloroaluminate melts: a new class of room-temperature ionic liquids for electrochemistry, spectroscopy and synthesis Inorganic Chemistry. ,vol. 13, pp. 1263- 1264 ,(1982) , 10.1021/IC00133A078
Helena L. Chum, V. R. Koch, L. L. Miller, R. A. Osteryoung, Electrochemical scrutiny of organometallic iron complexes and hexamethylbenzene in a room temperature molten salt Journal of the American Chemical Society. ,vol. 97, pp. 3264- 3265 ,(1975) , 10.1021/JA00844A081
Yi-Chia Lee, David L. Price, Larry A. Curtiss, Mark A. Ratner, Duward F. Shriver, Structure of the ambient temperature alkali metal molten salt AlCl[sub 3]/LiSCN The Journal of Chemical Physics. ,vol. 114, pp. 4591- 4594 ,(2001) , 10.1063/1.1344609
Weizhong Lv, Zhongkuan Luo, Hui Yang, Bo Liu, Wenjiang Weng, Jianhong Liu, Effect of processing conditions on sonochemical synthesis of nanosized copper aluminate powders. Ultrasonics Sonochemistry. ,vol. 17, pp. 344- 351 ,(2010) , 10.1016/J.ULTSONCH.2009.06.006