Removal of Phosphate from Aqueous Solution Using Alginate/Iron (III) Chloride Capsules: a Laboratory Study

作者: Hanna Siwek , Artur Bartkowiak , Małgorzata Włodarczyk , Katarzyna Sobecka

DOI: 10.1007/S11270-016-3128-0

关键词:

摘要: Binding phosphate at participation of alginate/FeCl3 capsules was studied with laboratory experiments. The hydrogel microcapsules were obtained the dropping-in method, by gelation sodium alginate water solution iron (III) chloride solution. Phosphate adsorption characteristics in a static batch system respect to changes contact time, initial phosphates concentration, pH solution, and temperature. After 24 h tests, average 87.5% ions removed from natural solutions; after 48 h, an equilibrium reached. data well fit Freundlich isotherm model. Parameter k isotherms amounted 43.4 104.7, whereas parameter n 0.362 0.476. course processes desorption aquatic phase, as pH, suggests that is major mechanism removal, simultaneously, but much lower degree, process precipitation released takes its place. Parameters calculated equation show using several times smaller amounts iron, it possible remove similar or bigger phosphorus than other adsorbents containing iron. adsorbent removes wide spectrum—from 4 10. Results suggest proposed has potential remediation contaminated waters phosphate.

参考文章(42)
H. Mimura, H. Hoshi, K. Akiba, Y. Onodera, Separation of americium from europium by biopolymer microcapsules enclosing Cyanex 301 extractant Journal of Radioanalytical and Nuclear Chemistry. ,vol. 247, pp. 375- 379 ,(2001) , 10.1023/A:1006770021710
David L. Correll, The role of phosphorus in the eutrophication of receiving waters: a review Journal of Environmental Quality. ,vol. 27, pp. 261- 266 ,(1998) , 10.2134/JEQ1998.00472425002700020004X
Seiki Tanada, Mineaki Kabayama, Naohito Kawasaki, Toru Sakiyama, Takeo Nakamura, Mamiko Araki, Takamichi Tamura, Removal of phosphate by aluminum oxide hydroxide. Journal of Colloid and Interface Science. ,vol. 257, pp. 135- 140 ,(2003) , 10.1016/S0021-9797(02)00008-5
F. Haghseresht, Shaobin Wang, D.D. Do, A novel lanthanum-modified bentonite, Phoslock, for phosphate removal from wastewaters Applied Clay Science. ,vol. 46, pp. 369- 375 ,(2009) , 10.1016/J.CLAY.2009.09.009
Senlin Tian, Peixi Jiang, Ping Ning, Yonghe Su, None, Enhanced adsorption removal of phosphate from water by mixed lanthanum/aluminum pillared montmorillonite Chemical Engineering Journal. ,vol. 151, pp. 141- 148 ,(2009) , 10.1016/J.CEJ.2009.02.006
Nina S. Dionisiou, Theodora Matsi, Νikolaos D. Misopolinos, Phosphorus Adsorption–Desorption on a Surfactant-Modified Natural Zeolite: A Laboratory Study Water Air and Soil Pollution. ,vol. 224, pp. 1362- 1372 ,(2013) , 10.1007/S11270-012-1362-7
Audrey-Flore Ngomsik, Agnès Bee, Jean-Michel Siaugue, Delphine Talbot, Valérie Cabuil, Gérard Cote, Co(II) removal by magnetic alginate beads containing Cyanex 272 Journal of Hazardous Materials. ,vol. 166, pp. 1043- 1049 ,(2009) , 10.1016/J.JHAZMAT.2008.11.109
D. Nayak, S. Lahiri, Biosorption of toxic, heavy, no-carrier-added radionuclides by calcium alginate beads Journal of Radioanalytical and Nuclear Chemistry. ,vol. 267, pp. 59- 65 ,(2005) , 10.1007/S10967-006-0009-9
Eric Van Hullebusch, Véronique Deluchat, Philippe M. Chazal, Michel Baudu, Environmental impact of two successive chemical treatments in a small shallow eutrophied lake: Part I. Case of aluminium sulphate. Environmental Pollution. ,vol. 120, pp. 617- 626 ,(2002) , 10.1016/S0269-7491(02)00192-6