Application of response surface methodology for optimization of azocarmine B removal by heterogeneous photo-Fenton process using hydroxy-iron–aluminum pillared bentonite
作者： Tianyuan Xu , Yun Liu , Fei Ge , Lin Liu , Yuting Ouyang
DOI: 10.1016/J.APSUSC.2013.05.098
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摘要: Abstract Hydroxy-iron–aluminum pillared bentonite (H-Fe–Al-B) was synthesized with ion exchange method, and its catalyst characteristics were analyzed by using X-ray diffraction (XRD) photoelectron spectrometry (XPS). The photo-Fenton catalytic activity of H-Fe–Al-B tested under different reaction condition azocarmine B (ACB) as model pollutant ultraviolet light (UV) irradiation. effects three operating variables, initial dye concentration, pH value H2O2 concentration on the decolorization efficiency ACB optimized response surface methodology (RSM) based Box–Behnken design. results showed that hydroxy aluminum iron ions intercalated into interlayer spaces successfully had high photocatalytic activity. Analysis variance (ANOVA) indicated proposed quadratic could be used to navigate design space. approximately in accordance experimental case correlation coefficients R2, R adj 2 pred 0.9996, 0.9991 0.9934, respectively. optimum conditions for 143.7 mg/L, 4.2 17.7 mM, predicted rate determined 99.6%. Confirmatory tests carried out 99.5% observed, which closely agreed value.
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sci-hub.se 参考文章(30)
Jianxi Zhu, Lizhong Zhu, Runliang Zhu, Baoliang Chen, MICROSTRUCTURE OF ORGANO-BENTONITES IN WATER AND THE EFFECT OF STERIC HINDRANCE ON THE UPTAKE OF ORGANIC COMPOUNDS Clays and Clay Minerals. ,vol. 56, pp. 144- 154 ,(2008) , 10.1346/CCMN.2008.0560202
Sami Sayadi, Abdelhamid Ghorbel, Wahiba Najjar, Samia Azabou, Catalytic wet peroxide photo-oxidation of phenolic olive oil mill wastewater contaminants: Part I. Reactivity of tyrosol over (Al–Fe)PILC Applied Catalysis B-environmental. ,vol. 74, pp. 11- 18 ,(2007) , 10.1016/J.APCATB.2007.01.007
Ruzhong Chen, Joseph J. Pignatello, Role of Quinone Intermediates as Electron Shuttles in Fenton and Photoassisted Fenton Oxidations of Aromatic Compounds Environmental Science & Technology. ,vol. 31, pp. 2399- 2406 ,(1997) , 10.1021/ES9610646
Jianxin Chen, Lizhong Zhu, UV-Fenton discolouration and mineralization of Orange II over hydroxyl-Fe-pillared bentonite Journal of Photochemistry and Photobiology A-chemistry. ,vol. 188, pp. 56- 64 ,(2007) , 10.1016/J.JPHOTOCHEM.2006.11.018
J. Herney-Ramirez, Miguel A. Vicente, Luis M. Madeira, Heterogeneous photo-Fenton oxidation with pillared clay-based catalysts for wastewater treatment: A review Applied Catalysis B-environmental. ,vol. 98, pp. 10- 26 ,(2010) , 10.1016/J.APCATB.2010.05.004
Jing Guo, Muthanna Al-Dahhan, Catalytic Wet Oxidation of Phenol by Hydrogen Peroxide over Pillared Clay Catalyst Industrial & Engineering Chemistry Research. ,vol. 42, pp. 2450- 2460 ,(2003) , 10.1021/IE020344T
Kumarasamy Murugesan, Ankur Dhamija, In-Hyun Nam, Young-Mo Kim, Yoon-Seok Chang, Decolourization of reactive black 5 by laccase: Optimization by response surface methodology Dyes and Pigments. ,vol. 75, pp. 176- 184 ,(2007) , 10.1016/J.DYEPIG.2006.04.020
George E P Box, Norman R Draper, Empirical Model-Building and Response Surfaces ,(1987)
H.M. Pinheiro, E. Touraud, O. Thomas, Aromatic amines from azo dye reduction: status review with emphasis on direct UV spectrophotometric detection in textile industry wastewaters Dyes and Pigments. ,vol. 61, pp. 121- 139 ,(2004) , 10.1016/J.DYEPIG.2003.10.009
Patricio Peralta-Zamora, Airton Kunz, Sandra Games de Moraes, Ronaldo Pelegrini, Patricia de Campos Moleiro, Juan Reyes, Nelson Duran, Degradation of reactive dyes I. A comparative study of ozonation, enzymatic and photochemical processes Chemosphere. ,vol. 38, pp. 835- 852 ,(1999) , 10.1016/S0045-6535(98)00227-6