The Electronic Spectra of Pyrene, Chrysene, Azulene, Coronene and Tetracene Crystals
作者： Jiro Tanaka
DOI: 10.1246/BCSJ.38.86
关键词:
摘要: The electronic absorption spectra of single crystals pyrene, chrysene, azulene, coronene and tetracene have been measured by a polarized light. Some crystal bands exhibit appreciable splittings changes in intensity relations according to the simple exciton theory. Those results are explained use second-order calculation without inclusion electron overlap effect. theoretical give fairly reasonable explanation spectra, it has shown that mixing excited states plays an essential role modifying from pattern free molecule.
csj.jp参考文章(16)
Donald S. McClure, Electronic Spectra of Molecules and Ions in Crystals Part I. Molecular Crystals Journal of Physics C: Solid State Physics. ,vol. 8, pp. 1- 47 ,(1959) , 10.1016/S0081-1947(08)60478-6
H.C. Wolf, The Electronic Spectra of Aromatic Molecular Crystals Solid State Physics. ,vol. 9, pp. 1- 81 ,(1959) , 10.1016/S0081-1947(08)60563-9
Graham R. Hunt, Ian G. Ross, Spectrum of azulene: Part II. The 7000-A and 3500-A absorption systems Journal of Molecular Spectroscopy. ,vol. 9, pp. 50- 78 ,(1962) , 10.1016/0022-2852(62)90212-6
J. M. Robertson, H. M. M. Shearer, G. A. Sim, D. G. Watson, The Crystal and Molecular Structure of Azulene Acta Crystallographica. ,vol. 15, pp. 1- 8 ,(1962) , 10.1107/S0365110X62000018
J. Ferguson, Absorption and Fluorescence Spectra of Crystalline Pyrene Journal of Chemical Physics. ,vol. 28, pp. 765- 768 ,(1958) , 10.1063/1.1744267
An X-Ray Analysis of the Structure of Chrysene Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 146, pp. 140- 153 ,(1934) , 10.1098/RSPA.1934.0143
Jiro Tanaka, The Electronic Spectra of Aromatic Molecular Crystals. II. The Crystal Structure and Spectra of Perylene Bulletin of the Chemical Society of Japan. ,vol. 36, pp. 1237- 1249 ,(1963) , 10.1246/BCSJ.36.1237
John Krc Jr, Crystallographic Data-45. Chrysene Analytical Chemistry. ,vol. 23, pp. 932- 933 ,(1951) , 10.1021/AC60054A033
G. C. Nieman, G. W. Robinson, Rapid Triplet Excitation Migration in Organic Crystals The Journal of Chemical Physics. ,vol. 37, pp. 2150- 2151 ,(1962) , 10.1063/1.1733439
Jerome W. Sidman, Donald S. McClure, Electronic and Vibrational States of Azulene The Journal of Chemical Physics. ,vol. 24, pp. 757- 763 ,(1956) , 10.1063/1.1742604