Monte Carlo simulation of the double layer at an electrode including the effect of a dielectric boundary
作者： M Alawneh , D Henderson , None
DOI: 10.1080/08927020601054068
关键词:
摘要: Monte Carlo values of the density profiles and related properties double layer formed by an electrolyte near a charged electrode are reported for cases where has dielectric coefficient greater, equal, smaller than that causes surface polarization can be represented electrostatic images. As expected, compared to case there is no boundary ions attracted or repelled if greater smaller, respectively, electrolyte. This effect most pronounced stronger 2:2 electrolytes 1:1 electrolytes. For both monovalent divalent at low concentrations.
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