Chapter 14 Formation of Unconventional Compounds and Catalysts in Magnesium-Containing Organic Films

作者: V.V. Smirnov , L.A. Tyurina , I.P. Beletskaya

DOI: 10.1016/S1079-4050(06)34014-8

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摘要: Low-temperature synthesis in metal-containing films is an original and promising field of organometallic chemistry. A classical Grignard reaction Mg–RX turned out to yield novel compounds composition RMg n X. The use cluster reagents their hydride analogues considerably extends the range objects processes chemistry organomagnesium makes it possible observe catalytic transformations hydrocarbons.

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