Kinetics of weight loss by thermal decomposition of xylan and lignin. Influence of experimental conditions

作者: Rafael Bilbao , Angela Millera , Jesús Arauzo

DOI: 10.1016/0040-6031(89)85051-8

关键词:

摘要: The kinetics of weight loss in the thermal decomposition xylan and lignin a nitrogen environment have been studied thermogravimetrically. data from this study are analysed light previous conclusions obtained with cellulose. results isothermal dynamic experiments at different heating rates related by using low (1.5 °C min−1) as reference.

参考文章(10)
Rafael Bilbao, Jesús Arauzo, Angela Millera, Kinetics of thermal decomposition of cellulose Thermochimica Acta. ,vol. 120, pp. 121- 131 ,(1987) , 10.1016/0040-6031(87)80211-3
Rafael Bilbao, Jesús Arauzo, Angela Millera, Kinetics of thermal decomposition of cellulose Thermochimica Acta. ,vol. 120, pp. 133- 141 ,(1987) , 10.1016/0040-6031(87)80212-5
G. Gyulai, E.J. Greenhow, Non-isothermal reaction kinetics Thermochimica Acta. ,vol. 5, pp. 481- 484 ,(1973) , 10.1016/0040-6031(73)80027-9
J.R. MacCallum, J. Tanner, A comparative study of some methods of assessing kinetic parameters from thermogravimetric analysis European Polymer Journal. ,vol. 6, pp. 907- 917 ,(1970) , 10.1016/0014-3057(70)90014-5
R. A. W. HILL, Rate equations in thermogravimetry. Nature. ,vol. 227, pp. 703- 704 ,(1970) , 10.1038/227703A0
A.F. Roberts, The heat of reaction during the pyrolysis of wood Combustion and Flame. ,vol. 17, pp. 79- 86 ,(1971) , 10.1016/S0010-2180(71)80141-4
F. Shafizadeh, Y.L. Fu, Pyrolysis of cellulose. Carbohydrate Research. ,vol. 29, pp. 113- 122 ,(1973) , 10.1016/S0008-6215(00)82074-1
J.R. MacCallum, J. Tanner, The kinetics of thermogravimetry European Polymer Journal. ,vol. 6, pp. 1033- 1039 ,(1970) , 10.1016/0014-3057(70)90035-2
V. M. Gorbatchev, V. A. Logvinenko, The correlation between isothermal and non-isothermal kinetics in thermogravimetry Journal of Thermal Analysis and Calorimetry. ,vol. 4, pp. 475- 477 ,(1972) , 10.1007/BF01913805
M. V. Ramiah, Thermogravimetric and differential thermal analysis of cellulose, hemicellulose, and lignin Journal of Applied Polymer Science. ,vol. 14, pp. 1323- 1337 ,(1970) , 10.1002/APP.1970.070140518