Copolymers of phenacyl methacrylate with glycidyl methacrylate: synthesis, characterization and monomer reactivity ratios

作者: Cengiz Soykan , Misir Ahmedzade , Mehmet Coşkun

DOI: 10.1016/S0014-3057(99)00230-X

关键词:

摘要: Abstract Copolymers with various proportions of phenacyl methacrylate (PAMA) and glycidyl (GMA) were prepared by free radical-polymerization in solution 1,4-dioxane using 2,2′-azobisisobutyronitrile as initiator at 70°C. The polymers characterized infrared 1H 13C nuclear magnetic resonance (NMR) spectroscopy. copolymer compositions determined 1H-NMR spectra. reactivity ratios calculated both Fineman–Ross Kelen–Tudos methods. Glass transition decomposition temperatures copolymers determined.

参考文章(16)
Paul J. Flory, Principles of polymer chemistry ,(1953)
Frank Alden Bovey, F. H. Winslow, Macromolecules: An Introduction to Polymer Science ,(1982)
R. M. Burns, Henry Fleming Payne, Organic Coating Technology ,(1954)
N.S. Allen, F. Catalina, C. Peinado, R. Sastre, J.L. Mateo, P.N. Green, Synthesis, characterization and photopolymerization activity of a novel thioxanthone monomer and photopolymers European Polymer Journal. ,vol. 23, pp. 985- 987 ,(1987) , 10.1016/0014-3057(87)90045-0
N. Grassie, B.J.D. Torrance, J.D. Fortune, J.D. Gemmell, Reactivity ratios for the copolymerization of acrylates and methacrylates by nuclear magnetic resonance spectroscopy Polymer. ,vol. 6, pp. 653- 658 ,(1965) , 10.1016/0032-3861(65)90048-0
Hans Georg Batz, Giselher Franzmann, Helmut Ringsdorf, Pharmakologisch aktive polymere, 5. Modellreaktionen zur umsetzung von pharmaka und enzymen mit monomeren und polymeren reaktiven estern Macromolecular Chemistry and Physics. ,vol. 172, pp. 27- 47 ,(1973) , 10.1002/MACP.1973.021720103
Morton Fineman, Sidney D. Ross, Linear method for determining monomer reactivity ratios in copolymerization Journal of Polymer Science. ,vol. 5, pp. 259- 262 ,(1950) , 10.1002/POL.1950.120050210
J.G. Hamilton, K.J. Ivin, L.C. Kuan-Essig, P. Watt, Detection of tacticity in polypropylenimine by 13C n.m.r. Polymer. ,vol. 16, pp. 763- 764 ,(1975) , 10.1016/0032-3861(75)90197-4