A review of the properties of polymer single crystals with defects within the macromolecular chain

摘要: Abstract The morphology, thermal behavior, and degradation pattern of solution-grown single crystals polymers with “constitutional” “configurational” chain defects within macromolecules are examined. Neither evidence rejection from the crystalline core nor influence distribution in on thickness crystal is observed. In contrast Flory's theory equilibrium crystallization random copolymers, some constitutional configurational must be incorporated into lattice as reticular imperfections. Some models able to explain manner which can accommodated polymer suggested discussed.