Stereochemistry of Substitution of the α-Dimethylamino Group by Dialkylzinc in Chiral Benzylferrocene
作者： Tatsuki Takahashi , Takashi Konno , Kenichi Ogata , Shin-ichi Fukuzawa
DOI: 10.1021/JO3012013
关键词:
摘要: The stereochemistry of the substitution α-dimethylamino group by dimethylzinc in presence acetyl chloride chiral benzylferrocene backbone was examined. reaction with bearing an o-bromo substituent at both ferrocene and phenyl ring proceeded inversion configuration, while either or retention configuration.
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