Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: a new class of metallacarbatranes and a monovalent thallium alkyl compound.
作者： Ahmed Al-Harbi , Yi Rong , Gerard Parkin
DOI: 10.1039/C3DT52163J
关键词:
摘要: Tris(2-pyridonyl)methanes may be synthesized via the reactions of respective 2-pyridone with CHX3 (X = Cl, Br) and K2CO3 in presence [Bu(n)4N]Br, followed by acid-catalyzed isomerization camphorsulfonic acid. These compounds provide access to a new class alkyl ligands that feature oxygen donors are capable forming metallacarbatranes monovalent thallium compound.
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