Selective Transformations of Triglycerides into Fatty Amines, Amides, and Nitriles by using Heterogeneous Catalysis
作者： Md. A. R. Jamil , S. M. A. Hakim Siddiki , Abeda Sultana Touchy , Md. Nurnobi Rashed , Sharmin Sultana Poly
关键词:
摘要: The use of triglycerides as an important class biomass is effective strategy to realize a more sustainable society. Herein, three heterogeneous catalytic methods are reported for the selective one-pot transformation into value-added chemicals: i) reductive amination fatty amines with aqueous NH3 under H2 promoted by ZrO2 -supported Pt clusters; ii) amidation gaseous catalyzed high-silica H-beta (Hβ) zeolite at 180 °C; iii) Hβ-promoted synthesis nitriles from and 220 °C. These widely applicable various (C4 -C18 skeletons) corresponding amines, amides, nitriles.
sci-hub.se 参考文章(64)
Dinesh Kumar, Amjad Ali, None, Direct synthesis of fatty acid alkanolamides and fatty acid alkyl esters from high free fatty acid containing triglycerides as lubricity improvers using heterogeneous catalyst Fuel. ,vol. 159, pp. 845- 853 ,(2015) , 10.1016/J.FUEL.2015.07.046
Christos Kordulis, Kyriakos Bourikas, Mantha Gousi, Eleana Kordouli, Alexis Lycourghiotis, Development of nickel based catalysts for the transformation of natural triglycerides and related compounds into green diesel: a critical review Applied Catalysis B-environmental. ,vol. 181, pp. 156- 196 ,(2016) , 10.1016/J.APCATB.2015.07.042
Michikazu Hara, Kiyotaka Nakajima, Keigo Kamata, None, Recent progress in the development of solid catalysts for biomass conversion into high value-added chemicals Science and Technology of Advanced Materials. ,vol. 16, pp. 034903- ,(2015) , 10.1088/1468-6996/16/3/034903
Iván Sorribes, Jose R. Cabrero-Antonino, Cristian Vicent, Kathrin Junge, Matthias Beller, Catalytic N-Alkylation of Amines Using Carboxylic Acids and Molecular Hydrogen. Journal of the American Chemical Society. ,vol. 137, pp. 13580- 13587 ,(2015) , 10.1021/JACS.5B07994
Dinesh Kumar, Soo Min Kim, Amjad Ali, None, One step synthesis of fatty acid diethanolamides and methyl esters from triglycerides using sodium doped calcium hydroxide as a nanocrystalline heterogeneous catalyst New Journal of Chemistry. ,vol. 39, pp. 7097- 7104 ,(2015) , 10.1039/C5NJ00388A
Tsung Min Kuo, Hakryul Kim, Ching T. Hou, Production of a novel compound, 7,10,12-trihydroxy-8(E)-octadecenoic acid from ricinoleic acid by Pseudomonas aeruginosa PR3. Current Microbiology. ,vol. 43, pp. 198- 203 ,(2001) , 10.1007/S002840010287
H. Maag, Fatty acid derivatives: Important surfactants for household, cosmetic and industrial purposes Journal of the American Oil Chemists' Society. ,vol. 61, pp. 259- 267 ,(1984) , 10.1007/BF02678778
Avelino Corma, Sara Iborra, Alexandra Velty, Chemical Routes for the Transformation of Biomass into Chemicals Chemical Reviews. ,vol. 107, pp. 2411- 2502 ,(2007) , 10.1021/CR050989D
Chen Zhao, Thomas Brück, Johannes A. Lercher, Catalytic deoxygenation of microalgae oil to green hydrocarbons Green Chemistry. ,vol. 15, pp. 1720- 1739 ,(2013) , 10.1039/C3GC40558C
Praveen Kumar Vemula, George John, Crops: A Green Approach toward Self-Assembled Soft Materials Accounts of Chemical Research. ,vol. 41, pp. 769- 782 ,(2008) , 10.1021/AR7002682