Structure of network polymers based on oligoisoprene dihydrazides and an epoxide oligomer

作者: V.V. Shilov , Yu.S. Lipatov , V.A. Bogdanovich , D.P. Kochetov , V.K. Grishchenko

DOI: 10.1016/0032-3950(83)90003-5

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摘要: Abstract Methods of wide and low angle X-ray diffraction have been used to study the special aspects microheterogeneous structure epoxydiene polymer networks synthesized from oligoisoprene dihydrazide epoxide oligomer ED-16. It is shown that characteristic such systems high level microphase separation components depending on MW starting oligomers. The nets formed posses a clearly marked ordered microregions with size between 6 7 nm.

参考文章(19)
W. Ruland, Über die Struktur amorpher Polymere Steinkopff. pp. 192- 205 ,(1975) , 10.1007/BFB0117186
S. N. Bagchi, R. Hosemann, Direct analysis of diffraction by matter North-Holland Pub. Co.. ,(1962)
P. Debye, A. M. Bueche, Scattering by an Inhomogeneous Solid Journal of Applied Physics. ,vol. 20, pp. 518- 525 ,(1949) , 10.1063/1.1698419
R. Perret, W. Ruland, X-ray small-angle scattering of glassy carbon Journal of Applied Crystallography. ,vol. 5, pp. 183- 187 ,(1972) , 10.1107/S0021889872009161
O. Kratky, I. Pilz, P.J. Schmitz, Absolute intensity measurement of small angle x-ray scattering by means of a standard sample Journal of Colloid and Interface Science. ,vol. 21, pp. 24- 34 ,(1966) , 10.1016/0095-8522(66)90078-X
K. Kurita, S. Miyazawa, M. Asukabe, E. Wada, Small-angle X-ray scattering from styrene-butadiene-styrene block copolymers Journal of Macromolecular Science, Part B. ,vol. 17, pp. 375- 388 ,(1980) , 10.1080/00222348008212819
Yuji Minoura, Shinzo Yamashita, Hiroshi Okamoto, Tadao Matsuo, Michiaki Izawa, Shun-Ich Kohmoto, Yuji Minoura, Shinzo Yamashita, Hiroshi Okamoto, Tadao Matsuo, Michiaki Izawa, Shun-Ich Kohmoto, Crosslinking and mechanical property of liquid rubber. I. Curative effect of aliphatic diols Journal of Applied Polymer Science. ,vol. 22, pp. 1817- 1844 ,(1978) , 10.1002/APP.1978.070220707
R. Bonart, E. H. Müller, Phase separation in urethane elastomers as judged by low-angle X-ray scattering. I. Fundamentals Journal of Macromolecular Science, Part B. ,vol. 10, pp. 177- 189 ,(1974) , 10.1080/00222347408219403
K. Dušek, J. Pleštil, F. Lednický, S. Luňák, Are cured epoxy resins inhomogeneous? Polymer. ,vol. 19, pp. 393- 397 ,(1978) , 10.1016/0032-3861(78)90243-4
E. W. Fischer, J. H. Wendorff, M. Dettenmaier, G. Lieser, I. Voigt-Martin, Chain conformation and structure in amorphous polymers as revealed by X-ray, neutron, light and electron diffraction Journal of Macromolecular Science, Part B. ,vol. 12, pp. 41- 59 ,(1976) , 10.1080/00222347608215172