One‐Step Synthesis of Collagen Hybrid Gold Nanoparticles and Formation on Egyptian‐like Gold‐Plated Archaeological Ivory

作者: Jolanda Spadavecchia , Emilande Apchain , Marie Albéric , Elisabeth Fontan , Ina Reiche

DOI: 10.1002/ANIE.201403567

关键词:

摘要: A one-step method is reported to synthesize hybrid gold nanoparticles (AuNPs) by reduction of HAuCl4 in acetic solution the presence collagen (Col), dicarboxylic acid-terminated polyethylene glycol (PEG), and cetyltetrammonium bromide (CTAB) mixed with hydoxyapatite (HAP) as surfactants. Such formation process AuNPs was shown be responsible for purple stains naturally formed on Egyptianizing archaeological gilded ivories from 8th BC Syria. The understanding this mechanism, which most likely involves a step AuNPs, allows establishing an authenticity marker ancient gold-plated ivories.

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