Mössbauer study of transformations of pyrite under conditions of coal liquefaction
作者： Pedro A. Montano , Arun S. Bommannavar , Vipul Shah
DOI: 10.1016/0016-2361(81)90223-4
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摘要: Abstract The Mossbauer effect is used to study in-situ transformations of pyrite under conditions coal liquefaction based on Illinois No. 6 from St. Clair County. A marked reduction observed at high temperatures in the isomer shift iron sulphides during liquefactions. By contrast pure do not show such a strong presence solvent and hydrogen. This may result covalent bonding between pyrrhotite surfaces coalderived liquid gases. Marked broadening linewidth Fe 1 − x S occurs above 300 °C stoichiometries pyrrhotites formed different runs were determined correlation was total amount sulphur deficiency . Coal-derived liquids are more active enhancing decomposition than tetralin. Both H 2 seem be actively involved process.
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sci-hub.se 参考文章(20)
H.H. Storch, C.O. Hawk, C.H. Fisher, A. Eisner, Hydrogenation and liquefaction of coal international conference on multimedia information networking and security. ,vol. 654, ,(1943)
David J. Vaughan, James R. Craig, Mineral chemistry of metal sulfides Cambridge University Press. ,(1978)
B. Granoff, P. A. Montano, Mineral matter effects in coal conversion Chemistry and Physics of Coal Utilization-1980. ,vol. 70, pp. 291- 308 ,(2008) , 10.1063/1.32945
O. C. Kistner, A. W. Sunyar, Evidence for Quadrupole Interaction ofFe57m, and Influence of Chemical Binding on Nuclear Gamma-Ray Energy Physical Review Letters. ,vol. 4, pp. 412- 415 ,(1960) , 10.1103/PHYSREVLETT.4.412
Sol Weller, M. G. Pelipetz, S. Friedman, H. H. Storch, Coal Hydrogenation Catalysts Batch Autoclave Tests Industrial & Engineering Chemistry. ,vol. 42, pp. 330- 334 ,(1950) , 10.1021/IE50482A032
J JOLY, Conversions of isopropanol by processed coal minerals and pyrite Journal of Catalysis. ,vol. 60, pp. 216- 227 ,(1979) , 10.1016/0021-9517(79)90144-1
Peter H. Given, Donald C. Cronauer, William Spackman, Harold L. Lovell, Alan Davis, Bimal Biswas, Dependence of coal liquefaction behaviour on coal characteristics. 2. Role of petrographic composition Fuel. ,vol. 54, pp. 40- 49 ,(1975) , 10.1016/0016-2361(75)90028-9
Dilip K. Mukherjee, Priya B. Chowdhury, Catalytic effect of mineral matter constituents in a North Assam coal on hydrogenation Fuel. ,vol. 55, pp. 4- 8 ,(1976) , 10.1016/0016-2361(76)90062-4
V. W. Hughes, H. G. Robinson, V. Beltran-Lopez, Upper Limit for the Anisotropy of Inertial Mass from Nuclear Resonance Experiments Physical Review Letters. ,vol. 4, pp. 342- 344 ,(1960) , 10.1103/PHYSREVLETT.4.342
Pedro A. Montano, Prem P. Vaishnava, James A. King, Edward N. Eisentrout, Mössbäuer study of decomposition of pyrite in hydrogen Fuel. ,vol. 60, pp. 712- 716 ,(1981) , 10.1016/0016-2361(81)90224-6