Air- and moisture-stable cationic (diphosphine)palladium(II) complexes as hydroamination catalysts: X-ray crystal structures of two [(diphosphine)Pd(NCMe)(OH2)]2+[OTf]−2 complexes

作者: Kelin Li , Peter N. Horton , Michael B. Hursthouse , King Kuok (Mimi) Hii

DOI: 10.1016/S0022-328X(02)02138-1

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摘要: A series of cationic (diphosphine)palladium(II) complexes have been prepared and fully characterized, including two crystal structures. These were evaluated as catalysts for the hydroamination acyclic alkenes. The reactivity is dependent on nature diphosphine ligand substituents amine alkene substrates.

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