Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

作者: Jigyoung Yi , Hye Mi Ahn , Jong Ho Yoon , Cheal Kim , Suk Joong Lee

DOI: 10.1039/C8NJ02214C

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摘要: A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent immobilization CuCl2 gave POP-Cu(II). This heterogeneous catalyst displayed outstanding olefin oxidation activity compared to its homogeneous analogue, suggesting that the degradation successfully inhibited by site isolation.

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