Three-dimensional graphene–Co3O4 cathodes for rechargeable Li–O2 batteries

作者: Jiakai Zhang , Pengfa Li , Zhenhua Wang , Jinshuo Qiao , David Rooney

DOI: 10.1039/C4TA05573J

关键词:

摘要: A three-dimensional (3D) graphene–Co3O4 electrode was prepared by a two-step method in which graphene initially deposited on Ni foam with Co3O4 then grown the resulting structure. Cross-linked nanosheets an open pore structure were fully and vertically distributed throughout skeleton. The free-standing binder-free monolithic used directly as cathode Li–O2 battery. This composite exhibited enhanced performance specific capacity of 2453 mA h g−1 at 0.1 cm−2 62 stable cycles 583 (1000 gcarbon−1). excellent electrochemical is associated unique architecture superior catalytic activity 3D electrode.

参考文章(55)
Jin-Hyon Lee, Robert Black, Guerman Popov, Ekaterina Pomerantseva, Feihong Nan, Gianluigi A. Botton, Linda F. Nazar, The role of vacancies and defects in Na0.44MnO2 nanowire catalysts for lithium–oxygen batteries Energy and Environmental Science. ,vol. 5, pp. 9558- 9565 ,(2012) , 10.1039/C2EE21543H
Jin Xie, Xiahui Yao, Ian P. Madden, De-En Jiang, Lien-Yang Chou, Chia-Kuang Tsung, Dunwei Wang, Selective Deposition of Ru Nanoparticles on TiSi2 Nanonet and Its Utilization for Li2O2 Formation and Decomposition Journal of the American Chemical Society. ,vol. 136, pp. 8903- 8906 ,(2014) , 10.1021/JA504431K
Wu Zhongshuai, Ren Wencai, Wen Lei, Gao Libo, Zhao Jinping, Chen Zongping, Zhou Guangmin, Li Feng, Cheng Hui-Ming, Graphene Anchored with Co 3 O 4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance ACS Nano. ,vol. 4, pp. 3187- 3194 ,(2010) , 10.1021/NN100740X
Yongye Liang, Yanguang Li, Hailiang Wang, Jigang Zhou, Jian Wang, Tom Regier, Hongjie Dai, Co3O4 Nanocrystals on Graphene as a Synergistic Catalyst for Oxygen Reduction Reaction arXiv: Materials Science. ,(2011) , 10.1038/NMAT3087
Xiaoming Ren, Sheng S. Zhang, Dat T. Tran, Jeffrey Read, Oxygen reduction reaction catalyst on lithium/air battery discharge performance Journal of Materials Chemistry. ,vol. 21, pp. 10118- 10125 ,(2011) , 10.1039/C0JM04170J
T. Yu, Y. W. Zhu, X. J. Xu, Z. X. Shen, P. Chen, C.-T. Lim, J. T.-L. Thong, C.-H. Sow, Controlled Growth and Field‐Emission Properties of Cobalt Oxide Nanowalls Advanced Materials. ,vol. 17, pp. 1595- 1599 ,(2005) , 10.1002/ADMA.200500322
Jie Xiao, Donghai Mei, Xiaolin Li, Wu Xu, Deyu Wang, Gordon L. Graff, Wendy D. Bennett, Zimin Nie, Laxmikant V. Saraf, Ilhan A. Aksay, Jun Liu, Ji-Guang Zhang, Hierarchically porous graphene as a lithium-air battery electrode. Nano Letters. ,vol. 11, pp. 5071- 5078 ,(2011) , 10.1021/NL203332E
Yan Lu, Zhaoyin Wen, Jun Jin, Yanming Cui, Meifen Wu, Shijiao Sun, Mesoporous carbon nitride loaded with Pt nanoparticles as a bifunctional air electrode for rechargeable lithium-air battery Journal of Solid State Electrochemistry. ,vol. 16, pp. 1863- 1868 ,(2012) , 10.1007/S10008-012-1640-8
Changzhou Yuan, Long Yang, Linrui Hou, Laifa Shen, Fang Zhang, Diankai Li, Xiaogang Zhang, Large-scale Co3O4 nanoparticles growing on nickel sheets via a one-step strategy and their ultra-highly reversible redox reaction toward supercapacitors Journal of Materials Chemistry. ,vol. 21, pp. 18183- 18185 ,(2011) , 10.1039/C1JM14173B
Yanming Cui, Zhaoyin Wen, Yu Liu, A free-standing-type design for cathodes of rechargeable Li–O2 batteries Energy and Environmental Science. ,vol. 4, pp. 4727- 4734 ,(2011) , 10.1039/C1EE02365A