Fatty acids, part 54. Some reactions of long-chain oxygenated acids with special reference to those furnishing furanoid acids
作者： F.D. Gunstone , R.C. Wijesundera
DOI: 10.1016/0009-3084(79)90088-4
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摘要: Abstract C18 furanoid acids are prepared from natural oxygenated by palladium (II)-catalysed cyclodehydrogenation, rearrangement of epoxides with iodopropane-sodium iodide-dimethylsulphoxide, and dehydration endoperoxides. Some reactions give mixed products but routes to the individual 10,13-, 9,12- 8,11-furans reported. The endoperoxide route leads speculation about biosynthesis acids.
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