O,N- Bidentate Ligands Co-Ordinated on Ru-Based Olefin Metathesis Catalysts

作者: B. D. Clercq , F. Verpoort

DOI: 10.1007/978-94-010-0066-6_8

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摘要: A new class of Schiff Base Ruthenium arene complexes has been prepared. These tested in ring-opening metathesis polymerisation (ROMP) and ring-closing (RCM) reactions. The results point out that without trimethylsilyldiazomethane (TMSD) very low activities are obtained. In case the activated with TMSD good yields obtained for RCM. Furthermore, a mechaniscm suggested.

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