摘要: The basic facts and fundamental properties of binary fullerene cocrystals are reviewed, focusing especially on solvates salts Buckminsterfullerene (C60), hydrates hydrophilic C60 derivatives. examined include the lattice structure presence orientational disorder and/or rotational dynamics (of both fullerenes cocrystallizing moieties), thermodynamic such as decomposition enthalpies, charge transport properties. Both molecular shed light extent intermolecular interactions in these solid-state systems. Comparison is carried out also with pristine fullerite solid phases functionalized C60. Interesting experimental findings simultaneous occurrence rotations constituent species, crystal morphologies reminiscent quasi-crystalline behaviour, observation proton conduction hydrate solids derivatives, production super-hard carbon materials by application high pressures solvated crystals.
frontiersin.org
harvard.edu
core.ac.uk
sci-hub.se 参考文章(81)
Efstratia Mitsari, Michela Romanini, Manesh Zachariah, Roberto Macovez, Solid state physicochemical properties and applications of organic and metallo-organic fullerene derivatives Current Organic Chemistry. ,vol. 20, pp. 645- 661 ,(2016) , 10.2174/1385272819666150730220449
J. Ye, M. Barrio, Ph. Negrier, N. Qureshi, I. B. Rietveld, R. Céolin, J. Ll. Tamarit, Orientational order in the stable buckminster fullerene solvate C60.2CBr2H2 European Physical Journal-special Topics. ,vol. 226, pp. 857- 867 ,(2017) , 10.1140/EPJST/E2016-60272-X
R. S. Ruoff, Doris S. Tse, Ripudaman Malhotra, Donald C. Lorents, Solubility of fullerene (C60) in a variety of solvents The Journal of Physical Chemistry. ,vol. 97, pp. 3379- 3383 ,(1993) , 10.1021/J100115A049
Bertil Sundqvist, Polymeric Fullerene Phases Formed Under Pressure Fullerene-Based Materials. pp. 85- 126 ,(2004) , 10.1007/B94380
Craig Collins, Melinda Duer, Jacek Klinowski, Molecular dynamics in crystalline C60·2CHBr3 Chemical Physics Letters. ,vol. 321, pp. 287- 291 ,(2000) , 10.1016/S0009-2614(00)00332-8
J. Rozen, F. Masin, R. Céolin, H. Szwarc, Dynamical model for the C 5 H 5 cycles in the C 60 ∙2 Fe( C 5 H 5 ) 2 solvate Physical Review B. ,vol. 70, pp. 144206- ,(2004) , 10.1103/PHYSREVB.70.144206
Mingguang Yao, Wen Cui, Mingrun Du, Junping Xiao, Xigui Yang, Shijie Liu, Ran Liu, Fei Wang, Tian Cui, Bertil Sundqvist, Bingbing Liu, Tailoring Building Blocks and Their Boundary Interaction for the Creation of New, Potentially Superhard, Carbon Materials Advanced Materials. ,vol. 27, pp. 3962- 3968 ,(2015) , 10.1002/ADMA.201500188
E. A. Katz, D. Faiman, K. Iakoubovskii, A. Isakina, K. A. Yagotintsev, M. A. Strzhemechny, I. Balberg, Effect of the disorder/order phase transition on the electrical and photoelectrical properties of C60 thin films Journal of Applied Physics. ,vol. 93, pp. 3401- 3406 ,(2003) , 10.1063/1.1556187
B. Sundqvist, Interaction between C60 and gases under pressure Low Temperature Physics. ,vol. 29, pp. 440- 444 ,(2003) , 10.1063/1.1542508
Brooks A. Jones, Antonio Facchetti, Michael R. Wasielewski, Tobin J. Marks, Tuning Orbital Energetics in Arylene Diimide Semiconductors. Materials Design for Ambient Stability of n-Type Charge Transport Journal of the American Chemical Society. ,vol. 129, pp. 15259- 15278 ,(2007) , 10.1021/JA075242E