Laser ablation synthesis of new gold arsenides using nano-gold and arsenic as precursors. Laser desorption ionisation time-of-flight mass spectrometry and spectrophotometry

作者: Lubomír Prokeš , Eladia María Peña-Méndez , José Elias Conde , Nagender Reddy Panyala , Milan Alberti

DOI: 10.1002/RCM.6815

关键词:

摘要: LAS of gold arsenides was performed using nano (NG) and arsenic as precursors. The clusters formed during laser desorption ionisation (LDI) were analysed by mass spectrometry using a quadrupole ion trap and reflectron time flight analyser to determine the stoichiometry. UV VIS spectrophotometry used follow possible hydrothermal synthesis arsenides. Over 450 species arsenide clusters 212 mixed chlorinated AumAsnClx were detected their stoichiometry determined.

参考文章(47)
Filippo Amato, Nagender Reddy Panyala, Petr Vašina, Pavel Souček, Josef Havel, Laser desorption ionisation quadrupole ion trap time-of-flight mass spectrometry of titanium-carbon thin films. Rapid Communications in Mass Spectrometry. ,vol. 27, pp. 1196- 1202 ,(2013) , 10.1002/RCM.6564
Stefan Gilb, Patrick Weis, Filip Furche, Reinhart Ahlrichs, Manfred M. Kappes, Structures of small gold cluster cations (Aun+, n<14): Ion mobility measurements versus density functional calculations The Journal of Chemical Physics. ,vol. 116, pp. 4094- 4101 ,(2002) , 10.1063/1.1445121
T. P. Lippa, S.-J. Xu, S. A. Lyapustina, J. M. Nilles, K. H. Bowen, Photoelectron spectroscopy of As−, As2−, As3−, As4−, and As5− Journal of Chemical Physics. ,vol. 109, pp. 10727- 10731 ,(1998) , 10.1063/1.477771
Katarína Švihlová, Lubomír Prokeš, Dana Skácelová, Eladia María Peña-Méndez, Josef Havel, Laser ablation synthesis of new gold tellurides using tellurium and nanogold as precursors. Laser desorption ionisation time‐of‐flight mass spectrometry Rapid Communications in Mass Spectrometry. ,vol. 27, pp. 1600- 1606 ,(2013) , 10.1002/RCM.6613
Zbyněk Špalt, Milan Alberti, Eladia Peña-Méndez, Josef Havel, Laser ablation generation of arsenic and arsenic sulfide clusters Polyhedron. ,vol. 24, pp. 1417- 1424 ,(2005) , 10.1016/J.POLY.2005.03.089
Martin Reich, Stephen E. Kesler, Satoshi Utsunomiya, Christopher S. Palenik, Stephen L. Chryssoulis, Rodney C. Ewing, Solubility of gold in arsenian pyrite Geochimica et Cosmochimica Acta. ,vol. 69, pp. 2781- 2796 ,(2005) , 10.1016/J.GCA.2005.01.011
A. Dmytruk, I. Dmitruk, I. Blonskyy, R. Belosludov, Y. Kawazoe, A. Kasuya, ZnO clusters: Laser ablation production and time-of-flight mass spectroscopic study Microelectronics Journal. ,vol. 40, pp. 218- 220 ,(2009) , 10.1016/J.MEJO.2008.07.010
Tunna Baruah, Mark R. Pederson, Rajendra R. Zope, M.R. Beltrán, Stability of Asn [n=4, 8, 20, 28, 32, 36, 60] cage structures Chemical Physics Letters. ,vol. 387, pp. 476- 480 ,(2004) , 10.1016/J.CPLETT.2004.02.063
Hironori Tsunoyama, Tatsuya Tsukuda, Magic numbers of gold clusters stabilized by PVP. Journal of the American Chemical Society. ,vol. 131, pp. 18216- 18217 ,(2009) , 10.1021/JA908188F
M Alcamı́, O Mó, M Yanez, None, Ab initio and density functional theory calculations on the protonated species of As4 clusters The Journal of Chemical Physics. ,vol. 108, pp. 8957- 8963 ,(1998) , 10.1063/1.476341