Ultraviolet photoelectron spectroscopy of poly(anthraquinone)s and poly(1,10-phenanthroline-3,8-diyl); their electronic structure and K-doped states
作者： T. Miyamae , M. Aoki , H. Etori , Y. Muramatsu , T. Saito
DOI: 10.1016/S0368-2048(97)00218-1
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摘要: Abstract Ultraviolet photoelectron spectra were measured for two classes of π-conjugated systems, poly(anthraquinone)s [poly(2-methylanthraquinone-1,4-diyl) [P(2Me-1,4-AQ)], poly(anthraquinone-1,5-diyl) [P(1,5-AQ)]], and poly(1,10-phenanthroline-3,8-diyl) (PPhen). Upon K-doping PPhen, new states, which could be assigned to bipolaron bands, appear in the originally empty energy gap. In case K-doped P(2Me-1,4-AQ), a state appeared gap region. On other hand, P(1,5-AQ) showed poor reactivity dopant comparison with P(2Me-1,4-AQ). The electronic structures neutral states these polymers analyzed using semiempirical MO calculations. structure PPhen-metal complex was also examined.
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sci-hub.se 参考文章(17)
P. M. Hoang, Steven Holdcroft, B. Lionel Funt, Preparation and Properties of Electrodes Modified by Polymeric Films with Pendant Anthraquinone Groups Journal of The Electrochemical Society. ,vol. 132, pp. 2129- 2133 ,(1985) , 10.1149/1.2114304
N.S. Hush, A.S. Cheung, P.R. Hilton, Binding energies of π- and “lone-pair”-levels in mono- and diaza-phenanthrenes and anthracenes: An He(I) photoelectron spectroscopic study Journal of Electron Spectroscopy and Related Phenomena. ,vol. 7, pp. 385- 400 ,(1975) , 10.1016/0368-2048(75)85003-1
Takakazu Yamamoto, Tsukasa Maruyama, Zhen-Hua Zhou, Takayori Ito, Takashi Fukuda, Yutaka Yoneda, Farida Begum, Tomiki Ikeda, Shintaro Sasaki, None, .pi.-Conjugated Poly(pyridine-2,5-diyl), Poly(2,2'-bipyridine-5,5'-diyl), and Their Alkyl Derivatives. Preparation, Linear Structure, Function as a Ligand to Form Their Transition Metal Complexes, Catalytic Reactions, n-Type Electrically Conducting Properties, Optical Properties, and Alignment on Substrates Journal of the American Chemical Society. ,vol. 116, pp. 4832- 4845 ,(1994) , 10.1021/JA00090A031
Koji Kamiya, Takayuki Miyamae, Makoto Oku, Kazuhiko Seki, Hiroo Inokuchi, Chizuko Tanaka, Jiro Tanaka, ULTRAVIOLET PHOTOEMISSION SPECTRA OF PERCHLORATE-DOPED CIS- AND TRANS-POLYACETYLENE The Journal of Physical Chemistry. ,vol. 100, pp. 16213- 16217 ,(1996) , 10.1021/JP953793Y
M Fahlman, P Bröms, DA Dos Santos, SC Moratti, N Johansson, K Xing, RH Friend, AB Holmes, JL Brédas, WR Salaneck, None, Electronic structure of pristine and sodium‐doped cyano‐substituted poly(2,5‐dihexyloxy‐p‐phenylenevinylene): A combined experimental and theoretical study Journal of Chemical Physics. ,vol. 102, pp. 8167- 8174 ,(1995) , 10.1063/1.469228
Takakazu Yamamoto, Hideki Etori, Poly(anthraquinone)s Having a .pi.-Conjugation System along the Main Chain. Synthesis by Organometallic Polycondensation, Redox Behavior, and Optical Properties Macromolecules. ,vol. 28, pp. 3371- 3379 ,(1995) , 10.1021/MA00113A042
Tetsuo Tsutsui, Noriyuki Takada, Shogo Saito, Etsuo Ogino, Sharply directed emission in organic electroluminescent diodes with an optical-microcavity structure Applied Physics Letters. ,vol. 65, pp. 1868- 1870 ,(1994) , 10.1063/1.113043
G. Lauer, W. Schäfer, A. Schweig, Assignment of the four lowest ionized states of p-benzoquinone and the question of “lone pair splitting” in this system Chemical Physics Letters. ,vol. 33, pp. 312- 315 ,(1975) , 10.1016/0009-2614(75)80164-3
Takayuki Miyamae, Daisuke Yoshimura, Hisao Ishii, Yukio Ouchi, Kazuhiko Seki, Takafumi Miyazaki, Tsuneaki Koike, Takakazu Yamamoto, Ultraviolet photoelectron spectroscopy of poly(pyridine‐2,5‐diyl), poly(2,2′‐bipyridine‐5,5′‐diyl), and their K‐doped states Journal of Chemical Physics. ,vol. 103, pp. 2738- 2744 ,(1995) , 10.1063/1.470508
G. Iucci, K. Xing, M. Lögdlund, M. Fahlman, W.R. Salaneck, Polaron to bipolaron transition in a conjugated polymer. Rubidium-doped poly(p-phenylenevinylene) Chemical Physics Letters. ,vol. 244, pp. 139- 144 ,(1995) , 10.1016/0009-2614(95)00921-P