Discrete Complexes of 3d Metals with Monodentate Bulky Alkoxide Ligands and Their Reactivity in Bond Activation and Bond Formation Reactions
作者： James A. Bellow , Maryam Yousif , Stanislav Groysman
DOI: 10.1080/02603594.2015.1108913
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摘要: This review focuses on the design, synthesis, and reactivity of low-coordinate base transition metal complexes supported by bulky alkoxide ligands. The unique electronic features ligands result in strongly electrophilic character at centers, which enhances metal-bound substrates facilitates their transformation. However, insufficiently tend to form oligomeric polymeric aggregates, thus circumventing well-defined isolated centers. examines first requirements for attainment mononuclear ligand environments. Coordination chemistry most prominent [OCR3] is discussed, with particular emphasis impact R group nuclearity resulting complex number bound it. Next, behavior such transfer ensuing examined. While several previously synthesized lig...
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