Clay-supported novel bimetallic core-shell Co-Pt and Ni-Pt nanocrystals with high catalytic activities.

作者: Dharmesh Varade , Kazutoshi Haraguchi

DOI: 10.1039/C4CP04194A

关键词:

摘要: We demonstrate the striking potential of exfoliated clay (synthetic hectorite; Laponite XLG) platelets to prepare bimetallic (Co–Pt and Ni–Pt) NCs with well-defined structures. Catalytic studies show a strong synergistic effect core–shell NCs; their catalytic activities are much higher than those monometallic other NCs.

参考文章(24)
F. Tao, M. E. Grass, Y. Zhang, D. R. Butcher, J. R. Renzas, Z. Liu, J. Y. Chung, B. S. Mun, M. Salmeron, G. A. Somorjai, Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles Science. ,vol. 322, pp. 932- 934 ,(2008) , 10.1126/SCIENCE.1164170
Jun-Min Yan, Xin-Bo Zhang, Tomoki Akita, Masatake Haruta, Qiang Xu, One-Step Seeding Growth of Magnetically Recyclable Au@Co Core−Shell Nanoparticles: Highly Efficient Catalyst for Hydrolytic Dehydrogenation of Ammonia Borane Journal of the American Chemical Society. ,vol. 132, pp. 5326- 5327 ,(2010) , 10.1021/JA910513H
Aicheng Chen, Peter Holt-Hindle, Platinum-based nanostructured materials: synthesis, properties, and applications. Chemical Reviews. ,vol. 110, pp. 3767- 3804 ,(2010) , 10.1021/CR9003902
G. Bishwa Bidita Varadwaj, K. M. Parida, Montmorillonite supported metal nanoparticles: an update on syntheses and applications RSC Advances. ,vol. 3, pp. 13583- 13593 ,(2013) , 10.1039/C3RA40520F
Chao Wang, Miaofang Chi, Dongguo Li, Dennis van der Vliet, Guofeng Wang, Qiyin Lin, John F. Mitchell, Karren L. More, Nenad M. Markovic, Vojislav R. Stamenkovic, Synthesis of Homogeneous Pt-Bimetallic Nanoparticles as Highly Efficient Electrocatalysts ACS Catalysis. ,vol. 1, pp. 1355- 1359 ,(2011) , 10.1021/CS200328Z
Deli Wang, Huolin L Xin, Hongsen Wang, Yingchao Yu, Eric Rus, David A Muller, Francis J DiSalvo, Hector D Abruña, None, Facile Synthesis of Carbon-Supported Pd–Co Core–Shell Nanoparticles as Oxygen Reduction Electrocatalysts and Their Enhanced Activity and Stability with Monolayer Pt Decoration Chemistry of Materials. ,vol. 24, pp. 2274- 2281 ,(2012) , 10.1021/CM203863D
Elena V. Shevchenko, Dmitri V. Talapin, Andrey L. Rogach, Andreas Kornowski, Markus Haase, Horst Weller, Colloidal Synthesis and Self-Assembly of CoPt3 Nanocrystals Journal of the American Chemical Society. ,vol. 124, pp. 11480- 11485 ,(2002) , 10.1021/JA025976L
Rajib Ghosh Chaudhuri, Santanu Paria, Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications Chemical Reviews. ,vol. 112, pp. 2373- 2433 ,(2012) , 10.1021/CR100449N
Zhufang Liu, Jenny E. Hu, Qi Wang, Karen Gaskell, Anatoly I. Frenkel, Gregory S. Jackson, Bryan Eichhorn, PtMo Alloy and MoOx@Pt Core-Shell Nanoparticles as Highly CO-Tolerant Electrocatalysts Journal of the American Chemical Society. ,vol. 131, pp. 6924- 6925 ,(2009) , 10.1021/JA901303D