In Situ Formation of a MoS2‐Based Inorganic–Organic Nanocomposite by Directed Thermal Decomposition
作者： John Djamil , Stefan A. W. Segler , Wolfgang Bensch , Ulrich Schürmann , Mao Deng
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摘要: Nanocomposites based on molybdenum disulfide (MoS2) and different carbon modifications are intensively investigated in several areas of applications due to their intriguing optical electrical properties. Addition a third element may enhance the functionality application such nanocomposites. Herein, we present facile synthetic approach directed thermal decomposition (Ph4P)(2)MoS4 generating MoS2 nanocomposites containing phosphorous. Decomposition at 250 degrees C yields composite material with significantly enlarged interlayer distances caused by situ formation Ph3PS bonded slabs through MoS bonds (Ph4P)(2)S molecules van der Waals gap, as was evidenced P-31 solid-state NMR spectroscopy. Visible-light-driven hydrogen generation demonstrates high catalytic performance materials.
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