The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role.
作者： Nuno A. G. Bandeira , Somenath Garai , Achim Müller , Carles Bo
DOI: 10.1039/C5CC06423F
关键词:
摘要: The mechanism for the hydration of CO2 within a Keplerate nanocapsule is presented. A network hydrogen bonds across water layers in first metal coordination sphere facilitates proton abstraction and nucleophilic addition water. highly acidic properties polyoxometalate cluster are crucial explaining catalysed hydration.
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