Ionic Strength Dependence of Formation Constants, Complexation of Molybdenum(VI) with Glutamic Acid

作者: Farrokh Gharib , Karim Zare , Kavosh Majlesi

DOI: 10.1021/JE000074Q

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摘要: The complexation of molybdenum(VI) with glutamic acid was investigated in aqueous solution ranging pH from 4 to 9, using polarimetric and spectrophotometric techniques. composition the complex determined by continuous variations method. It shown that forms a mononuclear 1:1 type MoO3L-2 at 5.8. protonation constants (using potentiometric technique) stability constant were 25 °C ionic strengths (0.1 1.0) mol dm-3 sodium perchlorate. dependence on strength is described Debye−Huckel-type equation.

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