Design and synthesis of bichromophores for nonlinear optical applications in polymer films
作者： Junkuo Gao , Yuanjing Cui , Jiancan Yu , Wenxin Lin , Zhiyu Wang
DOI: 10.1016/J.REACTFUNCTPOLYM.2011.01.009
关键词:
摘要: Three bichromophores were designed and synthesized by linking a vinylthiophene-conjugated chromophore with different tether groups via esterification. Second harmonic generation measurements of nonlinear polymer films revealed that the second coefficients containing bichromophore using 3-phenoxypropane-1,2-diyl succinic diester as group improved in comparison mono-chromophore-doped films. However, isophthalic ester decreased. Overall, results indicate has potential applications design synthesis multi-chromophoric dendrimers large macroscopic optical nonlinearity.
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