Phospha-guanidine I. Eine neue verbindungsklassemit zweifach-koordiniertem dreibindigem phosphor
作者： Kurt Issleib , Harry schmidt , Hinrich Meyer
DOI: 10.1016/S0022-328X(00)93328-X
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摘要: Abstract Bis-silylated phosphines react with carbodiimides giving phosphaguanidines through insertion into the PSi-bond. Depending on substituents R′ and R″ N,P -bis-silylated derivatives (I) or N′,N′ isomers (II) are formed, latter results from P,N -silyl migration formation of a PC double bond. (R = Me, Cy, t-Bu, Ph, p -Me 2 NC 4 H ;R′ Alkyl, Aryl e.g. ClC 6 The structures compounds I II discussed basis their NMR spectra reaction methanol leads to PH-functional . Treatment RP(SiMe 3 ) PhNCO is also discussed.
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sci-hub.se 参考文章(4)
R. Allmann, Kristallstruktur eines Phosphacyanins Angewandte Chemie. ,vol. 77, pp. 134- 134 ,(1965) , 10.1002/ANGE.19650770314
Rolf Appel, Klaus Geisler, Vereinfachte synthese von organosilylphosphinen Journal of Organometallic Chemistry. ,vol. 112, pp. 61- 64 ,(1976) , 10.1016/S0022-328X(00)89366-3
G. Becker, H. P. Beck, Bildung und Eigenschaften von Aoylphosphinen. III. Molekül‐ und KristallStruktur von Dipivaloylphosphin Zeitschrift für anorganische und allgemeine Chemie. ,vol. 430, pp. 77- 90 ,(1977) , 10.1002/ZAAC.19774300108
E. W. Abel, I. H. Sabherwal, Reactions of the silicon–phosphorus bond. Part I. Insertions in trimethylsilyldiphenylphosphine J. Chem. Soc. A. ,vol. 0, pp. 1105- 1108 ,(1968) , 10.1039/J19680001105