The Importance of Conformation in the Ozonolysis of Acetals
作者： Pierre Deslongchamps , Claude Moreau , Daniel Fréhel , Paul Atlani
DOI: 10.1139/V72-548
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摘要: Six gauche conformations are theoretically possible for an acetal function and only three of them are reactive toward ozone. Each oxygen of the acetal function must have an electron pair orbital oreitned antiperiplanar to the C—H bond in order to be reactive toward ozone.
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