Method and catalyst for the oxidative carbonylation of dienes
作者： Michael Schulz , Michael Slany , Martin Schäfer
DOI:
关键词:
摘要: The invention relates to a method for the oxidative carbonylation of dienes, according which one or more diolefins, primary, secondary tertiary alcohol, carbon monoxide and oxygen are reacted at temperature above 40 °C in catalyst system. system contains least metal compound eighth sub-group periodic table elements heteropolyacid general formula (I): [H]8+a-n[XMo12-a-bWbVaO40](H2O)y, where X = P, Si, As, Ge, Ti Zr, n 5 if 4 between 0 4, b 12, y 40. is present molar excess double relation metal.
lens.org 参考文章(5)
David R. Hamm, Kenneth A. Klingman, Robert J. Saxton, John H. Grate, Shannan L. Downey, Catalytic system for olefin oxidation to carbonyl products ,(1991)
Katarina Bergstad, Helena Grennberg, Jan-E. Bäckvall, Aerobic oxidations of conjugated dienes using a catalytic palladium(II)-quinone-heteropolyacid system for electron transfer from organic substrates to molecular oxygen Organometallics. ,vol. 17, pp. 45- 50 ,(1998) , 10.1021/OM970482W
Eit Drent, Selective oxidative carbonylation of conjugated dienes ,(1989)
Richard V. Lindsey, William W. Prichard, Oxidation of butadiene to furan ,(1980)
George W. Parshall, Zarah Ainbinder, Oxidative alkoxycarbonylation of olefins with palladium/heteropoly acid catalyst systems ,(1981)