SODIUM SULPHIDE AS A MILD AND SELECTIVE DESILYLATING REAGENT
作者： T. Schmittberger , D. Uguen
DOI: 10.1016/0040-4039(95)01549-3
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摘要: Abstract diphenyl- t -butoxysilyl ( i.e. DPTBOS) derivatives of alcohols are selectively cleaved by nonahydrated sodium sulphide in ethanol, the order reactivity being: primarysecondary⪢tertiary. The corresponding -butyldimethylsilyl and -butylsilyl remain unaffected these conditions.
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