An Air-Stable Densely Packed Phosphorene-Graphene Composite Toward Advanced Lithium Storage Properties

作者: Yu Zhang , Huanwen Wang , Zhongzhen Luo , Hui Teng Tan , Bing Li

DOI: 10.1002/AENM.201600453

关键词:

摘要: Phosphorene, monolayer or few‐layer black phosphorus (BP), has recently triggered strong scientific interest for lithium/sodium ion batteries (LIBs/SIBs) applications. However, there are still challenges regarding large‐scale fabrication, poor air stability. Herein, we report the high‐yield synthesis of phosphorene with good crystallinity and tunable size distributions via liquid‐phase exfoliation of bulk BP in formamide. Afterwards, a densely packed phosphorene–graphene composite (PG‐SPS, a packing density of 0.6 g cm− 3) is prepared …

参考文章(58)
Scott C. Warren, Adam H. Woomer, Tyler W. Farnsworth, Jun Hu, Rebekah A. Wells, Carrie L. Donley, Phosphorene: Synthesis, Scale-Up, and Quantitative Optical Spectroscopy. ACS Nano. ,vol. 9, pp. 8869- 8884 ,(2015) , 10.1021/ACSNANO.5B02599
M. T. Edmonds, A. Tadich, A. Carvalho, A. Ziletti, K. M. O’Donnell, S. P. Koenig, D. F. Coker, B. Özyilmaz, A. H. Castro Neto, M. S. Fuhrer, Creating a Stable Oxide at the Surface of Black Phosphorus ACS Applied Materials & Interfaces. ,vol. 7, pp. 14557- 14562 ,(2015) , 10.1021/ACSAMI.5B01297
Vishnu Sresht, Agílio A. H. Pádua, Daniel Blankschtein, Liquid-Phase Exfoliation of Phosphorene: Design Rules from Molecular Dynamics Simulations. ACS Nano. ,vol. 9, pp. 8255- 8268 ,(2015) , 10.1021/ACSNANO.5B02683
Wenping Sun, Xianhong Rui, Mani Ulaganathan, Srinivasan Madhavi, Qingyu Yan, Few-layered Ni(OH) 2 nanosheets for high-performance supercapacitors Journal of Power Sources. ,vol. 295, pp. 323- 328 ,(2015) , 10.1016/J.JPOWSOUR.2015.07.024
Fengnian Xia, Han Wang, Yichen Jia, Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics Nature Communications. ,vol. 5, pp. 4458- ,(2014) , 10.1038/NCOMMS5458
Damien Hanlon, Claudia Backes, Evie Doherty, Clotilde S. Cucinotta, Nina C. Berner, Conor Boland, Kangho Lee, Andrew Harvey, Peter Lynch, Zahra Gholamvand, Saifeng Zhang, Kangpeng Wang, Glenn Moynihan, Anuj Pokle, Quentin M. Ramasse, Niall McEvoy, Werner J. Blau, Jun Wang, Gonzalo Abellan, Frank Hauke, Andreas Hirsch, Stefano Sanvito, David D. O’Regan, Georg S. Duesberg, Valeria Nicolosi, Jonathan N. Coleman, Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics Nature Communications. ,vol. 6, pp. 8563- 8563 ,(2015) , 10.1038/NCOMMS9563
Jianming Xue, Wei Kang, Shijun Zhao, The potential application of phosphorene as an anode material in Li-ion batteries Journal of Materials Chemistry. ,vol. 2, pp. 19046- 19052 ,(2014) , 10.1039/C4TA04368E
Vy Tran, Ryan Soklaski, Yufeng Liang, Li Yang, Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus Physical Review B. ,vol. 89, pp. 235319- ,(2014) , 10.1103/PHYSREVB.89.235319
Jie Guan, Zhen Zhu, David Tománek, High Stability of Faceted Nanotubes and Fullerenes of Multiphase Layered Phosphorus: A Computational Study Physical Review Letters. ,vol. 113, pp. 226801- ,(2014) , 10.1103/PHYSREVLETT.113.226801
Te-Huan Liu, Chien-Cheng Chang, None, Anisotropic thermal transport in phosphorene: effects of crystal orientation Nanoscale. ,vol. 7, pp. 10648- 10654 ,(2015) , 10.1039/C5NR01821H