Stereoselective Synthesis of Alkenyl Silanes, Sulfones, Phosphine Oxides, and Nitroolefins by Radical C-S Bond Cleavage of Arylalkenyl Sulfides.
作者： Ya-mei Lin , Guo-ping Lu , Rong-kang Wang , Wen-bin Yi
DOI: 10.1021/ACS.ORGLETT.7B00126
关键词:
摘要: A radical-mediated approach has been introduced for the C–S bond activation of arylalkenyl sulfides. The protocol provides an efficient generation various alkenes including alkenyl silanes, sulfones, phosphine oxides, and nitroolefins. In most cases, these radical substitutions are performed under metal-free conditions with stereospecificity.
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