A potassium-ion selective electrode with valinomycin based poly(vinyl chloride) membrane and a poly(vinyl ferrocene) solid contact

作者: Peter C. Hauser , David W.L. Chiang , Graham A. Wright

DOI: 10.1016/0003-2670(94)00472-X

关键词:

摘要: The construction of an ion-selective electrode for potassium, employing valinomycin as carrier in a poly(vinyl chloride) membrane and ferrocene) solid contact between the metallic substrate, is described. performance this compared to electrodes coated-wire configuration conventional with aqueous internal reference electrolyte. Nernstian responses were obtained three types selectivities detection limits are very similar all electrodes. stabilities these investigated over first 20 days use. solid-contact showed significant improvement stability it approaches one.

参考文章(31)
Milena Koudelka, Colin G. Francis, Surface Modification of a Planar Electrochemical Microcell Analytica Chimica Acta. ,vol. 219, pp. 45- 54 ,(1989) , 10.1016/S0003-2670(00)80332-3
R.W. Cattrall, D.M. Drew, I.C. Hamilton, Some alkylphosphoric acid esters for use in coated-wire calcium-selective electrodes: Part I. Response characteristics Analytica Chimica Acta. ,vol. 76, pp. 269- 277 ,(1975) , 10.1016/S0003-2670(01)85398-8
A. Merz, Allen J. Bard, A Stable Surface Modified Platinum Electrode Prepared by Coating with Electroactive Polymer Journal of the American Chemical Society. ,vol. 100, pp. 3222- 3223 ,(1978) , 10.1021/JA00478A049
T.J. Cardwell, R.W. Cattrall, P.C. Hauser, I.C. Hamilton, A multi-ion sensor cell and data-acquisition system for flow injection analysis Analytica Chimica Acta. ,vol. 214, pp. 359- 366 ,(1988) , 10.1016/S0003-2670(00)80456-0
A. Hulanicki, M. Trojanowicz, Calcium-selective electrodes with pvc membranes and solid internal contacts Analytica Chimica Acta. ,vol. 87, pp. 411- 417 ,(1976) , 10.1016/S0003-2670(01)82269-8