作者: W.G. Henderson , E.F. Mooney
DOI: 10.1016/S0066-4103(08)60323-3
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摘要: Publisher Summary This chapter focuses on boron-11 nuclear magnetic resonance (NMR) spectroscopy. The theoretical considerations of chemical shifts are presented in the chapter. Tercovalent boron compounds, including substituted halides and aminoboranes described Later, association tercovalent compounds is discussed this also describes tetra-covalent compounds. Boron heterocycles can be divided into two distinct fields, effect ring strain 11 B shift correlation aromaticity with shift. borazoles has been investigated by several groups workers some have a review boron-nitrogen In co-ordination boron, most conflicting results obtained. It is, however, generally recognized that transformation sp 2 hybridization atom to 3 hybridized state complex formation high field. complexes boranes trihalides, simple phosphorus extensively investigated, possibly because presence B- 31 P coupling.