An impedance and chronocoulometric study of the adsorption of chloride and bromide ions on bismuth single crystal planes from solutions in methanol

作者: E Lust , M Väärtnôu

DOI: 10.1016/S0022-0728(97)00606-2

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摘要: The adsorption of Cl− and Br− ions on the (111), (001) (011) planes a bismuth single crystal electrode from solutions in methanol has been investigated by means differential capacity coulometric measurements. ionic charge due to specific obtained using mixed-electrolyte method. results have analysed some characteristics calculated simple virial isotherm classical inner layer model. It found that difference for various Bi is rather small it depends solvent nature quite complicated manner. analogous be close ethanol water, but much lower than 2-propanol.

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