Dipole bound and valence state coupling in argon-solvated nitromethane anions
作者： F. Lecomte , S. Carles , C. Desfrançois , M. A. Johnson
DOI: 10.1063/1.1326476
关键词:
摘要: The coupling between the dipole bound and valence electronic states of nitromethane anion has been investigated via Rydberg electron transfer spectroscopy field detachment bare argon-solvated anions. unique aspects system are highlighted by comparing solvation behavior with that acetonitrile, a in which state is well-isolated from resonance arising excess occupation its high lying lowest unoccupied molecular orbital.
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