Investigation of physicochemical and electrochemical properties of recast Nafion nanocomposite membranes using different loading of zirconia nanoparticles for proton exchange membrane fuel cell applications
作者： Mohammad Javad Parnian , Soosan Rowshanzamir , Jafar Alipour Moghaddam
DOI: 10.1016/J.MSET.2018.06.008
关键词:
摘要: Abstract In this work, Nafion ionomer was prepared by a dissolution method in high pressure-temperature autoclave reactor using membrane sources. Zirconia nanoparticles were synthesized the microwave assisted gel combustion method. The characterized XRD and FESEM, then added to solution prepare recast nanocomposite membranes (R-Nafion/ZrO 2 ) with different loading of ZrO nanoparticles. Membranes recasting terms water uptake, dimensional stability, ionic conductivity, chemical stability (Fenton test), tensile strength, scanning electron microscope (SEM) techniques. obtained results for compared filler-free commercial membranes. showed higher mechanical oxidative stabilities hygroscopic zirconia resulted proton conductivity at temperatures comparison pure membrane. defect free, dense microstructure, good dispersion membranes’ matrix. illustrated have physicochemical electrochemical properties PEMFC applications.
sci-hub.se 参考文章(81)
G. Gnana, Kee Suk, Polymer Nanocomposites - Fuel Cell Applications InTech. ,(2011) , 10.5772/15440
H‐F. Xu, X. Wang, Z‐G. Shao, I‐M. Hsing, Recycling and regeneration of used perfluorosulfonic membranes for polymer electrolyte fuel cells Journal of Applied Electrochemistry. ,vol. 32, pp. 1337- 1340 ,(2002) , 10.1023/A:1022636000888
A. Saccà, I. Gatto, A. Carbone, R. Pedicini, E. Passalacqua, ZrO2–Nafion composite membranes for polymer electrolyte fuel cells (PEFCs) at intermediate temperature Journal of Power Sources. ,vol. 163, pp. 47- 51 ,(2006) , 10.1016/J.JPOWSOUR.2005.12.062
G. Alberti, M. Casciola, D. Capitani, A. Donnadio, R. Narducci, M. Pica, M. Sganappa, Novel Nafion–zirconium phosphate nanocomposite membranes with enhanced stability of proton conductivity at medium temperature and high relative humidity Electrochimica Acta. ,vol. 52, pp. 8125- 8132 ,(2007) , 10.1016/J.ELECTACTA.2007.07.019
Pucheng Pei, Huicui Chen, Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review Applied Energy. ,vol. 125, pp. 60- 75 ,(2014) , 10.1016/J.APENERGY.2014.03.048
R. Hammami, Z. Ahamed, K. Charradi, Z. Beji, I. Ben Assaker, J. Ben Naceur, B. Auvity, G. Squadrito, R. Chtourou, Elaboration and characterization of hybrid polymer electrolytes Nafion–TiO2 for PEMFCs International Journal of Hydrogen Energy. ,vol. 38, pp. 11583- 11590 ,(2013) , 10.1016/J.IJHYDENE.2013.02.013
Yılser Devrim, Huseyin Devrim, PEM fuel cell short stack performances of silica doped nanocomposite membranes International Journal of Hydrogen Energy. ,vol. 40, pp. 7870- 7878 ,(2015) , 10.1016/J.IJHYDENE.2014.11.018
Zhao Wang, Haolin Tang, Huijie Zhang, Ming Lei, Rui Chen, Pan Xiao, Mu Pan, Synthesis of Nafion/CeO2 hybrid for chemically durable proton exchange membrane of fuel cell Journal of Membrane Science. ,vol. 421, pp. 201- 210 ,(2012) , 10.1016/J.MEMSCI.2012.07.014
J YUAN, G ZHOU, H PU, Preparation and properties of Nafion®/hollow silica spheres composite membranes Journal of Membrane Science. ,vol. 325, pp. 742- 748 ,(2008) , 10.1016/J.MEMSCI.2008.08.050
Yonggang Jin, Shizhang Qiao, Lei Zhang, Zhi Ping Xu, Simon Smart, Joao C Diniz da Costa, Gao Qing Lu, None, Novel Nafion composite membranes with mesoporous silica nanospheres as inorganic fillers Journal of Power Sources. ,vol. 185, pp. 664- 669 ,(2008) , 10.1016/J.JPOWSOUR.2008.08.094