Kinetics of the reactions of the hydroxyl radical with xylenes
作者： J. M. Nicovich , R. L. Thompson , A. R. Ravishankara
DOI: 10.1021/J150620A012
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摘要: Absolute rate constants for the reactions of hydroxyl radical with o-, m- and p-xylene are reported temperature interval 250 less than or equal to T 970 K. Three major reaction pathways observed. At 320 K, electrophilic addition OH ring is dominant, while above 500 K abstraction hydrogen atoms from side-chain CH/sub 3/ groups dominant. In range 400 system complicated because reverse decomposition product.
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