Organometallic Halide Perovskite Synthesis in Polymer Melt for Improved Stability in High Humidity
作者： John P. Murphy , Jessica M. Andriolo , Brandon M. Ross , Gary F. Wyss , Nicole E. Zander
DOI: 10.1557/ADV.2016.379
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摘要: A new organometallic halide perovskite (OHP) synthesis method, whereby a polymer melt is used to thermodynamically drive the reaction that forms OHP crystallites, demonstrated. The method allows for facile encapsulation of moisture-sensitive without loss simplicity during fabrication, which makes materials so attractive photovoltaic industry. Degradation crystallites embedded in polystyrene matrix was studied using UV-Vis absorbance over period several days. degrade as result reversible nature crystallites. After reversion precursors (PbI 2 and CH 3 NH I) I irreversibly degrades [2] allowing degradation be tracked via optical interrogation. Additionally, surface morphology elemental analysis fabricated samples carried out SEM/EDS techniques.
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sci-hub.se 参考文章(15)
Makhsud I. Saidaminov, Ahmed L. Abdelhady, Banavoth Murali, Erkki Alarousu, Victor M. Burlakov, Wei Peng, Ibrahim Dursun, Lingfei Wang, Yao He, Giacomo Maculan, Alain Goriely, Tom Wu, Omar F. Mohammed, Osman M. Bakr, High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization Nature Communications. ,vol. 6, pp. 7586- 7586 ,(2015) , 10.1038/NCOMMS8586
Giacomo Maculan, Arif D. Sheikh, Ahmed L. Abdelhady, Makhsud I. Saidaminov, Md Azimul Haque, Banavoth Murali, Erkki Alarousu, Omar F. Mohammed, Tom Wu, Osman M. Bakr, CH3NH3PbCl3 Single Crystals: Inverse Temperature Crystallization and Visible-Blind UV-Photodetector. Journal of Physical Chemistry Letters. ,vol. 6, pp. 3781- 3786 ,(2015) , 10.1021/ACS.JPCLETT.5B01666
Jae Hoon Yun, Inhwa Lee, Taek-Soo Kim, Min Jae Ko, Jin Young Kim, Hae Jung Son, Synergistic enhancement and mechanism study of mechanical and moisture stability of perovskite solar cells introducing polyethylene-imine into the CH3NH3PbI3/HTM interface Journal of Materials Chemistry. ,vol. 3, pp. 22176- 22182 ,(2015) , 10.1039/C5TA06008G
Bertrand Philippe, Byung-Wook Park, Rebecka Lindblad, Johan Oscarsson, Sareh Ahmadi, Erik M. J. Johansson, Håkan Rensmo, Chemical and Electronic Structure Characterization of Lead Halide Perovskites and Stability Behavior under Different Exposures—A Photoelectron Spectroscopy Investigation Chemistry of Materials. ,vol. 27, pp. 1720- 1731 ,(2015) , 10.1021/ACS.CHEMMATER.5B00348
M. M. Lee, J. Teuscher, T. Miyasaka, T. N. Murakami, H. J. Snaith, Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Science. ,vol. 338, pp. 643- 647 ,(2012) , 10.1126/SCIENCE.1228604
DHARAMVIR SINGH AHLAWAT, STUDY OF BAND GAP ENERGY AND THERMAL PROPERTIES OF PbI2 BY PHOTOACOUSTIC SPECTROSCOPY Modern Physics Letters B. ,vol. 26, pp. 1250098- ,(2012) , 10.1142/S0217984912500984
Kangning Liang, David B. Mitzi, Michael T. Prikas, Synthesis and Characterization of Organic−Inorganic Perovskite Thin Films Prepared Using a Versatile Two-Step Dipping Technique Chemistry of Materials. ,vol. 10, pp. 403- 411 ,(1998) , 10.1021/CM970568F
Amalie Dualeh, Peng Gao, Sang Il Seok, Mohammad Khaja Nazeeruddin, Michael Grätzel, Thermal Behavior of Methylammonium Lead- trihalide Perovskite Photovoltaic Light Harvesters Chemistry of Materials. ,vol. 26, pp. 6160- 6164 ,(2014) , 10.1021/CM502468K
Akihiro Kojima, Kenjiro Teshima, Yasuo Shirai, Tsutomu Miyasaka, Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Journal of the American Chemical Society. ,vol. 131, pp. 6050- 6051 ,(2009) , 10.1021/JA809598R
Jinli Yang, Braden D. Siempelkamp, Dianyi Liu, Timothy L. Kelly, Investigation of CH3NH3PbI3 Degradation Rates and Mechanisms in Controlled Humidity Environments Using in Situ Techniques ACS Nano. ,vol. 9, pp. 1955- 1963 ,(2015) , 10.1021/NN506864K