Oxoiron(IV)-mediated Baeyer–Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes
作者： Dóra Lakk-Bogáth , Gábor Speier , József Kaizer
DOI: 10.1039/C5NJ02093J
关键词:
摘要: In this communication we describe detailed mechanistic studies on the [FeII(CH3CN)(N4Py)(ClO4)]ClO4-catalyzed (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methyl-amine) Baeyer–Villiger oxidation of cyclohexanones by dioxygen with cooxidation various aldehydes, including kinetics formation and reactivity trapped spectroscopically characterized oxoiron(IV) intermediate.
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