Comparative study of microstructure, electric properties and conductivity for NiO and PNN modified Pb(Zn1/3Nb2/3)O3–PbZrO3–PbTiO3 ceramics
作者： Mupeng Zheng , Yudong Hou , Mankang Zhu , Ming Zhang , Hui Yan
DOI: 10.1016/J.MATERRESBULL.2013.12.061
关键词:
摘要: The comparative studies of NiO and Pb(Ni1/3Nb2/3)O3 (PNN) added Pb(Zn1/3Nb2/3)O3–PbZrO3–PbTiO3 (PZN–PZT) with the same content level Ni ions have been performed. On basis XRD TEM analysis, it is clear that introduction induces a phase transformation from morphotropic boundary (MPB) to tetragonal side, corresponding grain size increases greatly. In comparison, system PNN addition remains MPB structure, slightly. According analysis temperature dependencies dielectric constant AC conductivity, combined observed evolution trend ferroelectric loops, reasonable deduce two types substitution behaviors coexist in PZN–PZT system. doping Ni2+ can not only substitute for Ti4+, Zr4+ Nb5+ inequivalence replacement, but also Zn2+ equivalence replacement.
elsevier.com
sci-hub.se 参考文章(21)
Arvind Hallival, T. R. Shrout, Preparation of lead-based ferroelectric relaxors for capacitors American Ceramic Society Bulletin. ,vol. 66, pp. 704- 711 ,(1987)
Xinhua Zhu, Jianmin Zhu, Shunhua Zhou, Zhiguo Liu, Naiben Ming, Zhongyan Meng, Ferroelectric Domain Structures and their Morphology Evolution in Pb(Ni1/3Nb2/3)O3–PbZrO3–PbTiO3 Piezoelectric Ceramics Modified by Bismuth and Zinc Substitutions Journal of the American Ceramic Society. ,vol. 91, pp. 227- 234 ,(2007) , 10.1111/J.1551-2916.2007.02003.X
Feng Gao, Li-hong Cheng, Rong-zi Hong, Jiaji Liu, Chun-juan Wang, Changsheng Tian, Crystal structure and piezoelectric properties of xPb(Mn1/3Nb2/3)O3–(0.2−x)Pb(Zn1/3Nb2/3)O3–0.8Pb(Zr0.52Ti0.48)O3 ceramics Ceramics International. ,vol. 35, pp. 1719- 1723 ,(2009) , 10.1016/J.CERAMINT.2008.09.001
C. A. Randall, D. J. Barber, R. W. Whatmore, Ferroelectric domain configurations in a modified-PZT ceramic Journal of Materials Science. ,vol. 22, pp. 925- 931 ,(1987) , 10.1007/BF01103531
Shujun Zhang, Sung-Min Lee, Dong-Ho Kim, Ho-Yong Lee, Thomas R. Shrout, Characterization of Mn-modified Pb(Mg1∕3Nb2∕3)O3–PbZrO3–PbTiO3 single crystals for high power broad bandwidth transducers Applied Physics Letters. ,vol. 93, pp. 122908- 122908 ,(2008) , 10.1063/1.2992081
Chang-Bun Yoon, Seung-Ho Lee, Sung-Mi Lee, Hyoun-Ee Kim, Co‐firing of PZN‐PZT Flextensional Actuators Journal of the American Ceramic Society. ,vol. 87, pp. 1663- 1668 ,(2004) , 10.1111/J.1551-2916.2004.01663.X
Chang-Bun Yoon, Gun-Tae Park, Hyoun-Ee Kim, Jungho Ryu, Piezoelectric ultrasonic motor by co-extrusion process Sensors and Actuators A-physical. ,vol. 121, pp. 515- 519 ,(2005) , 10.1016/J.SNA.2005.03.013
M.-P. Zheng, Y.-D. Hou, F.-Y. Xie, J. Chen, M.-K. Zhu, H. Yan, Effect of valence state and incorporation site of cobalt dopants on the microstructure and electrical properties of 0.2PZN–0.8PZT ceramics Acta Materialia. ,vol. 61, pp. 1489- 1498 ,(2013) , 10.1016/J.ACTAMAT.2012.11.026
Jian Luo, Yet-Ming Chiang, Rowland M. Cannon, Nanometer-thick surficial films in oxides as a case of prewetting. Langmuir. ,vol. 21, pp. 7358- 7365 ,(2005) , 10.1021/LA0505420
Y.D. Hou, P.X. Lu, M.K. Zhu, X.M. Song, J.L. Tang, B. Wang, H. Yan, Effect of Cr2O3 addition on the structure and electrical properties of Pb((Zn1/3Nb2/3)0.20(Zr0.50Ti0.50)0.80)O3 ceramics Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 116, pp. 104- 108 ,(2005) , 10.1016/J.MSEB.2004.09.015