The diffusion and trapping of hydrogen in steel

作者: R.A Oriani

DOI: 10.1016/0001-6160(70)90078-7

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摘要: Abstract The mobility of dissolved hydrogen in an iron lattice having a population extraordinary, or trapping, sites for is analyzed under the assumption local equilibrium between mobile and trapped populations. It shown that at low coverage trapping usual solutions diffusion equations can be used to analyze experimental results effective diffusivity function trap density magnitude depth. In domain which activity not linear fractional occupation population, concept phenomenological becomes non-operational equation must solved with terms sources sinks, as done by McNabb Foster. Values number depth are obtained applying relevant selected data on variety steels without cold work. lead suggestion absence work solid-solid interfaces more important than dislocations loci sites, cold-worked steels, microcrack surfaces trapping.

参考文章(11)
Lawrence S. Darken, Physical chemistry of metals ,(1953)
John Crank, The mathematics of diffusion ,(1956)
M.J Hordon, B.L Averbach, Precision density measurements on deformed Copper and Aluminum single crystals Acta Metallurgica. ,vol. 9, pp. 247- 249 ,(1961) , 10.1016/0001-6160(61)90074-8
F Garofalo, H.A Wriedt, Density change in an austenitic stainless steel deformed in tension or compression Acta Metallurgica. ,vol. 10, pp. 1007- 1012 ,(1962) , 10.1016/0001-6160(62)90069-X
J.J Kramer, G.M Pound, R.F Mehl, The free energy of formation and the interfacial enthalpy in pearlite Acta Metallurgica. ,vol. 6, pp. 763- 771 ,(1958) , 10.1016/0001-6160(58)90051-8
LAWRENCE S. DARKEN, RODNEY P. SMITH, Behavior of Hydrogen in Steel During and After Immersion in Acid Corrosion. ,vol. 5, pp. 1- 16 ,(1949) , 10.5006/0010-9312-5.1.1
H.L. Eschbach, F. Gross, S. Schulien, Permeability measurements with gaseous hydrogen for various steels Vacuum. ,vol. 13, pp. 543- 547 ,(1963) , 10.1016/0042-207X(63)90541-4
Robert C. Frank, Don E. Swets, David L. Fry, Mass Spectrometer Measurements of the Diffusion Coefficient of Hydrogen in Steel in the Temperature Range of 25°–90°C Journal of Applied Physics. ,vol. 29, pp. 892- 898 ,(1958) , 10.1063/1.1723324
J. C. M. Li, R. A. Oriani, L. S. Darken, The Thermodynamics of Stressed Solids Zeitschrift für Physikalische Chemie. ,vol. 49, pp. 271- 290 ,(1966) , 10.1524/ZPCH.1966.49.3_5.271