Lattice model of ionic liquid confined by metal electrodes.
作者： Matheus Girotto , Rodrigo M. Malossi , Alexandre P. dos Santos , Yan Levin
DOI: 10.1063/1.5013337
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摘要: We study, using Monte Carlo simulations, the density profiles and differential capacitance of ionic liquids confined by metal electrodes. To compute the electrostatic energy, we use the recently developed approach based on periodic Green's functions. The method also allows us to easily calculate the induced charge on the electrodes permitting an efficient implementation of simulations in a constant electrostatic potential ensemble. To speed up the simulations further, we model the ionic liquid as a lattice Coulomb gas and precalculate …
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